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| 28.07.2012 | 16:00 | Falkirk FC | - | Stirling Albion FC | 3:0 (1:0) | |
| 16:00 | Montrose FC | - | Inverurie Loco Works | 4:2 (1:1) | ||
| 16:00 | Peterhead FC | - | East Fife FC | 1:2 (0:1) | ||
| 16:00 | Elgin City | - | Arbroath FC | 5:7 (1:5) | ||
| 16:00 | Forfar Athletic | - | Dunfermline Athletic | 3:2 (1:2) | ||
| 16:00 | Wick Academy FC | - | Raith Rovers | 2:4 (0:1) | ||
| 16:00 | Cowdenbeath FC | - | Alloa Athletic | 3:1 (1:1, 1:1, 1:1) i.E. | ||
| 16:00 | East Stirlingshire FC | - | Ayr United | 3:1 (2:0) | ||
| 16:00 | Greenock Morton FC | - | Albion Rovers | 2:0 (0:0) | ||
| 16:00 | Berwick Rangers | - | Queen's Park FC | 2:3 (0:0, 1:1, 2:2) i.E. | ||
| 16:00 | Dumbarton FC | - | Queen Of The South | 0:1 (0:0) | ||
| 16:00 | Hamilton Academical | - | Airdrie United FC | 0:1 (0:0) | ||
| 16:00 | Stranraer FC | - | Stenhousemuir FC | 1:2 (0:1) | ||
| 16:00 | Annan Athletic | - | Livingston FC | 1:0 (0:0) | ||
| 16:00 | Clyde FC | - | Partick Thistle | 0:1 (0:0) | ||
| 29.07.2012 | 16:05 | Brechin City FC | - | Rangers FC | 1:2 (1:1, 1:1) n.V. |
