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| 19.09.1965 | CA Osasuna | - | Barakaldo CF | 1:0 | ||
| Sporting Gijón | - | UE Lleida | 2:1 | |||
| RC Celta | - | Racing Santander | 2:1 | |||
| Deportivo La Coruña | - | Burgos CF | 1:0 | |||
| UP Langreo | - | Real Sociedad | 0:1 | |||
| CF Badalona | - | SD Indautxu | 3:1 | |||
| CD Condal | - | CE Europa | 2:1 | |||
| CE L'Hospitalet | - | Real Oviedo | 1:4 | |||
| CD Badajoz | - | CD Tenerife | 1:0 | |||
| Real Murcia | - | Hércules CF | 1:2 | |||
| Rayo Vallecano | - | Cádiz CF | 1:0 | |||
| Levante UD | - | UD Melilla | 7:0 | |||
| Recreativo Huelva | - | Algeciras CF | 1:0 | |||
| CF Calvo Sotelo | - | Real Valladolid | 3:0 | |||
| Granada CF | - | CD Constància | 3:0 | |||
| CA Ceuta | - | CD Mestalla | 2:2 |
| 1 | |||||||||
| # | Mannschaft | Sp. | S. | U. | N. | Tore | Dif. | Pk. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Sporting Gijón | 3 | 3 | 0 | 0 | 8:3 | 5 | 6:0 |
| 2 |
|
Real Sociedad | 3 | 2 | 1 | 0 | 6:3 | 3 | 5:1 |
| 3 |
|
Real Oviedo | 3 | 2 | 0 | 1 | 8:4 | 4 | 4:2 |
| 4 |
|
Deportivo La Coruña | 3 | 2 | 0 | 1 | 6:4 | 2 | 4:2 |
|
RC Celta | 3 | 2 | 0 | 1 | 6:4 | 2 | 4:2 | |
| 6 |
|
SD Indautxu | 3 | 2 | 0 | 1 | 3:3 | 0 | 4:2 |
| 7 |
|
CD Condal | 3 | 2 | 0 | 1 | 4:4 | 0 | 4:2 |
| 8 |
|
Racing Santander | 3 | 2 | 0 | 1 | 5:3 | 2 | 4:2 |
| 9 |
|
CF Badalona | 3 | 1 | 1 | 1 | 4:3 | 1 | 3:3 |
| 10 |
|
UE Lleida | 3 | 1 | 0 | 2 | 4:3 | 1 | 2:4 |
| 11 |
|
CE L'Hospitalet | 3 | 1 | 0 | 2 | 4:7 | -3 | 2:4 |
| 12 |
|
Burgos CF | 3 | 1 | 0 | 2 | 3:5 | -2 | 2:4 |
| 13 |
|
CA Osasuna | 3 | 1 | 0 | 2 | 1:3 | -2 | 2:4 |
| 14 |
|
CE Europa | 3 | 1 | 0 | 2 | 2:5 | -3 | 2:4 |
| 15 |
|
Barakaldo CF | 3 | 0 | 0 | 3 | 1:7 | -6 | 0:6 |
| 16 |
|
UP Langreo | 3 | 0 | 0 | 3 | 1:5 | -4 | 0:6 |
| 2 | |||||||||
| # | Mannschaft | Sp. | S. | U. | N. | Tore | Dif. | Pk. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Granada CF | 3 | 3 | 0 | 0 | 7:1 | 6 | 6:0 |
| 2 |
|
CF Calvo Sotelo | 3 | 3 | 0 | 0 | 9:3 | 6 | 6:0 |
| 3 |
|
Levante UD | 3 | 2 | 1 | 0 | 9:0 | 9 | 5:1 |
| 4 |
|
Rayo Vallecano | 3 | 2 | 0 | 1 | 4:1 | 3 | 4:2 |
| 5 |
|
Hércules CF | 3 | 2 | 0 | 1 | 3:2 | 1 | 4:2 |
| 6 |
|
Real Murcia | 3 | 2 | 0 | 1 | 4:3 | 1 | 4:2 |
| 7 |
|
Recreativo Huelva | 3 | 2 | 0 | 1 | 5:2 | 3 | 4:2 |
| 8 |
|
CA Ceuta | 3 | 1 | 1 | 1 | 3:5 | -2 | 3:3 |
| 9 |
|
Cádiz CF | 3 | 1 | 0 | 2 | 3:3 | 0 | 2:4 |
| 10 |
|
CD Mestalla | 3 | 0 | 2 | 1 | 3:5 | -2 | 2:4 |
| 11 |
|
CD Badajoz | 3 | 1 | 0 | 2 | 2:5 | -3 | 2:4 |
| 12 |
|
CD Constància | 3 | 1 | 0 | 2 | 1:10 | -9 | 2:4 |
| 13 |
|
Real Valladolid | 3 | 1 | 0 | 2 | 3:7 | -4 | 2:4 |
| 14 |
|
CD Tenerife | 3 | 1 | 0 | 2 | 7:2 | 5 | 2:4 |
| 15 |
|
UD Melilla | 3 | 0 | 0 | 3 | 2:13 | -11 | 0:6 |
| 16 |
|
Algeciras CF | 3 | 0 | 0 | 3 | 0:3 | -3 | 0:6 |
