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| 03.01.2025 | 19:00 | Pontevedra CF | - | RCD Mallorca | 3:0 (1:0) | |
| 19:00 | Granada CF | - | Getafe CF | 0:1 (0:0, 0:0, 0:1) n.V. | ||
| 19:00 | Racing Ferrol | - | Rayo Vallecano | 1:3 (0:2) | ||
| 04.01.2025 | 15:30 | SD Huesca | - | Real Betis | 0:1 (0:1) | |
| 16:30 | CD Tenerife | - | CA Osasuna | 1:2 (1:2) | ||
| 17:30 | UD Almería | - | Sevilla FC | 4:1 (0:1) | ||
| 19:00 | UD Barbastro | - | FC Barcelona | 0:4 (0:2) | ||
| 21:30 | UD Logroñés | - | Athletic Club | 3:4 (0:0, 0:0, 0:0) i.E. | ||
| 21:30 | Marbella FC | - | Atlético Madrid | 0:1 (0:1) | ||
| 05.01.2025 | 12:00 | Ourense CF | - | Real Valladolid | 3:2 (2:2) | |
| 12:00 | Elche CF | - | UD Las Palmas | 4:0 (1:0) | ||
| 15:30 | SD Ponferradina | - | Real Sociedad | 0:2 (0:0) | ||
| 15:30 | Racing Santander | - | RC Celta | 2:3 (1:1) | ||
| 15:30 | FC Cartagena | - | CD Leganés | 1:2 (1:1) | ||
| 06.01.2025 | 19:00 | Deportiva Minera | - | Real Madrid | 0:5 (0:3) | |
| 07.01.2025 | 21:00 | CD Eldense | - | Valencia CF | 0:2 (0:2) |
