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| 19.10.2005 | 20:30 | SD Eibar | - | CD Alavés | 1:0 (1:0) | |
| 20.10.2005 | 20:00 | CD Alcoyano | - | RCD Mallorca | 4:1 (2:0) | |
| 20:00 | CE L'Hospitalet | - | Gimnàstic de Tarragona | 4:3 (0:2) | ||
| 20:30 | Real Unión | - | Athletic Bilbao | 0:1 (0:0) | ||
| 20:30 | Burgos CF | - | Racing Santander | 1:0 (0:0) | ||
| 20:45 | Logroñés CF | - | UE Lleida | 0:1 (0:0, 0:0) n.V. | ||
| 21:00 | Zamora CF | - | Real Sociedad | 2:0 (1:0, 1:1, 1:1) i.E. | ||
| 21:00 | Albacete | - | Cádiz CF | 1:3 (1:1, 1:1) n.V. | ||
| 21:00 | CD Baza | - | Málaga CF | 4:3 (1:1, 1:1, 1:1) i.E. | ||
| 21:00 | Xerez CD | - | CD Numancia | 3:2 (1:1) | ||
| 21:30 | SD Tenisca | - | RC Celta | 1:3 (1:2) | ||
| 22:00 | Rayo Vallecano | - | Getafe CF | 1:2 (0:2) | ||
| 22:00 | Alicante CF | - | Real Zaragoza | 5:6 (0:0, 0:0, 1:1) i.E. | ||
| 22:00 | UD Las Palmas | - | Atlético Madrid | 0:1 (0:0) |
