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| H | SD Ponferradina | - | CD Lugo | 1:1 | ||
| R | CD Lugo | - | SD Ponferradina | 6:0 | ||
| H: 22.09.1994 | R: 05.10.1994 | Sieger: CD Lugo | ||||
| H | Caudal Deportivo | - | Real Avilés | 1:2 | ||
| R | Real Avilés | - | Caudal Deportivo | 0:2 | ||
| H: 28.09.1994 | R: 05.10.1994 | Sieger: Caudal Deportivo | ||||
| H | Polideportivo Ejido | - | Mármol Macael CD | 1:1 | ||
| R | Mármol Macael CD | - | Polideportivo Ejido | 0:0 | ||
| H: 28.09.1994 | R: 06.10.1994 | Sieger: Mármol Macael CD | ||||
| H | Málaga CF | - | Real Jaén | 1:3 | ||
| R | Real Jaén | - | Málaga CF | 0:0 | ||
| H: 28.09.1994 | R: 05.10.1994 | Sieger: Real Jaén | ||||
| H | SD Noja | - | Gimnástica Torrelavega | 1:1 | ||
| R | Gimnástica Torrelavega | - | SD Noja | 1:2 | ||
| H: 28.09.1994 | R: 05.10.1994 | Sieger: SD Noja | ||||
| H | Utebo FC | - | CE L'Hospitalet | 3:0 | ||
| R | CE L'Hospitalet | - | Utebo FC | 3:1 | ||
| H: 05.10.1994 | R: 13.10.1994 | Sieger: Utebo FC | ||||
| H | Andorra CF | - | FC Andorra | 1:2 | ||
| R | FC Andorra | - | Andorra CF | 2:0 | ||
| H: 05.10.1994 | R: 13.10.1994 | Sieger: FC Andorra | ||||
| H | Terrassa FC | - | UDA Gramenet | 0:1 | ||
| R | UDA Gramenet | - | Terrassa FC | 3:0 | ||
| H: 05.10.1994 | R: 21.10.1994 | Sieger: UDA Gramenet | ||||
| H | UE Rubí | - | AEC Manlleu | 1:1 | ||
| R | AEC Manlleu | - | UE Rubí | 5:1 | ||
| H: 05.10.1994 | R: 12.10.1994 | Sieger: AEC Manlleu | ||||
| H | UE Sant Andreu | - | Gimnàstic de Tarragona | 1:1 | ||
| R | Gimnàstic de Tarragona | - | UE Sant Andreu | 3:1 | ||
| H: 05.10.1994 | R: 12.10.1994 | Sieger: Gimnàstic de Tarragona | ||||
| H | UE Figueres | - | Girona FC | 0:2 | ||
| R | Girona FC | - | UE Figueres | 1:3 | ||
| H: 05.10.1994 | R: 12.10.1994 | Sieger: UE Figueres | ||||
| H | CE Sabadell | - | CE Premià | 2:0 | ||
| R | CE Premià | - | CE Sabadell | 1:1 | ||
| H: 05.10.1994 | R: 13.10.1994 | Sieger: CE Sabadell | ||||
| H | CD Numancia | - | CD Alavés | 3:0 | ||
| R | CD Alavés | - | CD Numancia | 2:2 | ||
| H: 05.10.1994 | R: 12.10.1994 | Sieger: CD Numancia | ||||
| H | Recreativo Huelva | - | CP Cacereño | 2:1 | ||
| R | CP Cacereño | - | Recreativo Huelva | 1:1 | ||
| H: 05.10.1994 | R: 12.10.1994 | Sieger: Recreativo Huelva | ||||
| H | Bergantiños FC | - | Racing Ferrol | 0:6 | ||
| R | Racing Ferrol | - | Bergantiños FC | 1:0 | ||
| H: 05.10.1994 | R: 12.10.1994 | Sieger: Racing Ferrol | ||||
| H | Peña Deportiva | - | CD Castellón | 0:1 | ||
| R | CD Castellón | - | Peña Deportiva | 3:1 | ||
| H: 05.10.1994 | R: 12.10.1994 | Sieger: CD Castellón | ||||
| H | Tomelloso CF | - | Real Murcia | 2:2 | ||
| R | Real Murcia | - | Tomelloso CF | 2:0 | ||
| H: 05.10.1994 | R: 12.10.1994 | Sieger: Real Murcia | ||||
| H | CD Hullera | - | UP Langreo | 0:0 | ||
| R | UP Langreo | - | CD Hullera | 3:1 | ||
| H: 05.10.1994 | R: 12.10.1994 | Sieger: UP Langreo | ||||
| H | Benidorm CD | - | Elche CF | 2:1 | ||
| R | Elche CF | - | Benidorm CD | 1:1 | ||
| H: 05.10.1994 | R: 12.10.1994 | Sieger: Benidorm CD | ||||
| H | SD Beasain | - | CD Tudelano | 3:0 | ||
| R | CD Tudelano | - | SD Beasain | 2:2 | ||
| H: 05.10.1994 | R: 12.10.1994 | Sieger: SD Beasain | ||||
| H | Barakaldo CF | - | CD Palencia | 1:0 | ||
| R | CD Palencia | - | Barakaldo CF | 2:0 | ||
| H: 05.10.1994 | R: 12.10.1994 | Sieger: CD Palencia | ||||
| H | Talavera CF | - | CF Fuenlabrada | 1:2 | ||
| R | CF Fuenlabrada | - | Talavera CF | 2:2 | ||
| H: 05.10.1994 | R: 12.10.1994 | Sieger: CF Fuenlabrada | ||||
| H | Pinoso CF | - | CD Alcoyano | 1:2 | ||
| R | CD Alcoyano | - | Pinoso CF | 0:0 | ||
| H: 05.10.1994 | R: 13.10.1994 | Sieger: CD Alcoyano | ||||
| H | Sestao SC | - | Club Bermeo | 2:1 | ||
| R | Club Bermeo | - | Sestao SC | 1:3 | ||
| H: 05.10.1994 | R: 20.10.1994 | Sieger: Sestao SC | ||||
| H | CD Cieza | - | Cartagena FC | 1:0 | ||
| R | Cartagena FC | - | CD Cieza | 7:0 | ||
| H: 05.10.1994 | R: 12.10.1994 | Sieger: Cartagena FC | ||||
| H | CD Manchego | - | Real Aranjuez | 2:1 | ||
| R | Real Aranjuez | - | CD Manchego | 1:3 | ||
| H: 05.10.1994 | R: 12.10.1994 | Sieger: CD Manchego | ||||
| H | Levante UD | - | Ontinyent CF | 2:1 | ||
| R | Ontinyent CF | - | Levante UD | 2:0 | ||
| H: 05.10.1994 | R: 12.10.1994 | Sieger: Ontinyent CF | ||||
| H | Real Ávila CF | - | UD SS Reyes | 1:1 | ||
| R | UD SS Reyes | - | Real Ávila CF | 2:0 | ||
| H: 05.10.1994 | R: 12.10.1994 | Sieger: UD SS Reyes | ||||
| H | Águilas CF | - | Yeclano CF | 1:0 | ||
| R | Yeclano CF | - | Águilas CF | 4:1 | ||
| H: 05.10.1994 | R: 12.10.1994 | Sieger: Yeclano CF | ||||
| H | CD Maspalomas | - | CD Corralejo | 1:2 | ||
| R | CD Corralejo | - | CD Maspalomas | 3:1 | ||
| H: 05.10.1994 | R: 12.10.1994 | Sieger: CD Corralejo | ||||
| H | Granada CF | - | UD Melilla | 3:2 | ||
| R | UD Melilla | - | Granada CF | 0:0 | ||
| H: 05.10.1994 | R: 12.10.1994 | Sieger: Granada CF | ||||
| H | CD San Fernando | - | Xerez CD | 3:2 | ||
| R | Xerez CD | - | CD San Fernando | 1:2 | ||
| H: 05.10.1994 | R: 12.10.1994 | Sieger: CD San Fernando | ||||
| H | CD San Roque | - | Cádiz CF | 0:2 | ||
| R | Cádiz CF | - | CD San Roque | 2:0 | ||
| H: 05.10.1994 | R: 12.10.1994 | Sieger: Cádiz CF | ||||
| H | Almería CF | - | CP Almería | 1:1 | ||
| R | CP Almería | - | Almería CF | 2:2 | ||
| H: 05.10.1994 | R: 13.10.1994 | Sieger: Almería CF | ||||
| H | CDC Moscardó | - | CD Móstoles | 4:1 | ||
| R | CD Móstoles | - | CDC Moscardó | 3:1 | ||
| H: 05.10.1994 | R: 12.10.1994 | Sieger: CDC Moscardó | ||||
| H | Écija Balompié | - | Córdoba CF | 1:0 | ||
| R | Córdoba CF | - | Écija Balompié | 2:0 | ||
| H: 05.10.1994 | R: 12.10.1994 | Sieger: Córdoba CF | ||||
| H | UD Realejos | - | UD Las Palmas | 2:3 | ||
| R | UD Las Palmas | - | UD Realejos | 7:0 | ||
| H: 05.10.1994 | R: 13.10.1994 | Sieger: UD Las Palmas | ||||
| H | UD Orotava | - | CD Mensajero | 3:3 | ||
| R | CD Mensajero | - | UD Orotava | 2:0 | ||
| H: 06.10.1994 | R: 20.10.1994 | Sieger: CD Mensajero | ||||
