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| H | SD Compostela | - | UE Lleida | 1:2 (1:1) | ||
| R | UE Lleida | - | SD Compostela | 4:1 (2:1) | ||
| H: 10.10.1993 | R: 02.11.1993 | Sieger: UE Lleida | ||||
| H | CP Mérida | - | Rayo Vallecano | 1:0 (0:0) | ||
| R | Rayo Vallecano | - | CP Mérida | 1:1 (0:0) | ||
| H: 12.10.1993 | R: 14.11.1993 | Sieger: CP Mérida | ||||
| H | Almería CF | - | Espanyol Barcelona | 0:2 (0:0) | ||
| R | Espanyol Barcelona | - | Almería CF | 5:1 (3:0) | ||
| H: 21.10.1993 | R: 03.11.1993 | Sieger: Espanyol Barcelona | ||||
| H | Cádiz CF | - | Real Oviedo | 0:2 (0:0) | ||
| R | Real Oviedo | - | Cádiz CF | 4:0 (2:0) | ||
| H: 26.10.1993 | R: 13.11.1993 | Sieger: Real Oviedo | ||||
| H | Athletic Bilbao | - | Real Zaragoza | 0:2 (0:1) | ||
| R | Real Zaragoza | - | Athletic Bilbao | 1:1 (1:0) | ||
| H: 27.10.1993 | R: 04.11.1993 | Sieger: Real Zaragoza | ||||
| H | Talavera CF | - | Racing Santander | 2:0 (1:0) | ||
| R | Racing Santander | - | Talavera CF | 3:2 (0:0) | ||
| H: 27.10.1993 | R: 03.11.1993 | Sieger: Talavera CF | ||||
| H | Palamós CF | - | CD Toledo | 0:0 | ||
| R | CD Toledo | - | Palamós CF | 1:0 | ||
| H: 27.10.1993 | R: 03.11.1993 | Sieger: CD Toledo | ||||
| H | Elche CF | - | Real Betis | 2:1 (0:1) | ||
| R | Real Betis | - | Elche CF | 5:0 (3:0) | ||
| H: 27.10.1993 | R: 04.11.1993 | Sieger: Real Betis | ||||
| H | Real Murcia | - | Real Valladolid | 0:3 (0:2) | ||
| R | Real Valladolid | - | Real Murcia | 3:1 (2:1) | ||
| H: 27.10.1993 | R: 14.11.1993 | Sieger: Real Valladolid | ||||
| H | Hércules CF | - | Real Sociedad | 1:1 (1:1) | ||
| R | Real Sociedad | - | Hércules CF | 0:0 (0:0) | ||
| H: 27.10.1993 | R: 03.11.1993 | Sieger: Real Sociedad | ||||
| H | RC Celta | - | Albacete | 4:0 (2:0) | ||
| R | Albacete | - | RC Celta | 4:1 (1:1) | ||
| H: 27.10.1993 | R: 04.11.1993 | Sieger: RC Celta | ||||
| H | Polideportivo Ejido | - | UD Salamanca | 3:0 | ||
| R | UD Salamanca | - | Polideportivo Ejido | 4:1 n.V. | ||
| H: 27.10.1993 | R: 04.11.1993 | Sieger: Polideportivo Ejido | ||||
| H | Getafe CF | - | CD Logroñés | 0:1 (0:0) | ||
| R | CD Logroñés | - | Getafe CF | 2:1 (2:0) | ||
| H: 27.10.1993 | R: 04.11.1993 | Sieger: CD Logroñés | ||||
| H | CD Castellón | - | Sevilla FC | 2:0 (2:0) | ||
| R | Sevilla FC | - | CD Castellón | 3:0 (1:0, 2:0) n.V. | ||
| H: 16.11.1993 | R: 24.11.1993 | Sieger: Sevilla FC | ||||
