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| H | Atlético Madrileño | - | Real Sociedad | 2:2 | ||
| R | Real Sociedad | - | Atlético Madrileño | 3:2 | ||
| H: 04.10.1989 | R: 25.10.1989 | Sieger: Real Sociedad | ||||
| H | Barcelona Atlètic | - | Cádiz CF | 1:1 | ||
| R | Cádiz CF | - | Barcelona Atlètic | 3:1 i.E. | ||
| H: 04.10.1989 | R: 01.11.1989 | Sieger: Cádiz CF | ||||
| H | Real Betis | - | CD Castellón | 2:0 | ||
| R | CD Castellón | - | Real Betis | 2:1 | ||
| H: 04.10.1989 | R: 25.10.1989 | Sieger: Real Betis | ||||
| H | Elche CF | - | Sporting Gijón | 0:0 | ||
| R | Sporting Gijón | - | Elche CF | 3:1 i.E. | ||
| H: 04.10.1989 | R: 25.10.1989 | Sieger: Sporting Gijón | ||||
| H | Xerez CD | - | CD Málaga | 1:1 | ||
| R | CD Málaga | - | Xerez CD | 2:0 | ||
| H: 04.10.1989 | R: 25.10.1989 | Sieger: CD Málaga | ||||
| H | Recreativo Huelva | - | Real Oviedo | 1:0 | ||
| R | Real Oviedo | - | Recreativo Huelva | 4:1 | ||
| H: 04.10.1989 | R: 25.10.1989 | Sieger: Real Oviedo | ||||
| H | CE Sabadell | - | Sevilla FC | 1:0 | ||
| R | Sevilla FC | - | CE Sabadell | 1:1 | ||
| H: 04.10.1989 | R: 01.11.1989 | Sieger: CE Sabadell | ||||
| H | Sestao SC | - | RC Celta | 0:2 | ||
| R | RC Celta | - | Sestao SC | 1:1 | ||
| H: 04.10.1989 | R: 25.10.1989 | Sieger: RC Celta | ||||
| H | CD Tenerife | - | Rayo Vallecano | 2:2 | ||
| R | Rayo Vallecano | - | CD Tenerife | 1:3 | ||
| H: 04.10.1989 | R: 25.10.1989 | Sieger: CD Tenerife | ||||
