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| H | Hércules CF | - | Recreativo Huelva | 2:1 | ||
| R | Recreativo Huelva | - | Hércules CF | 2:0 | ||
| H: 11.12.1985 | R: 08.01.1986 | Sieger: Recreativo Huelva | ||||
| H | UD Las Palmas | - | CD Castellón | 1:1 | ||
| R | CD Castellón | - | UD Las Palmas | 4:2 | ||
| H: 11.12.1985 | R: 08.01.1986 | Sieger: CD Castellón | ||||
| H | UE Lleida | - | Rayo Vallecano | 1:0 | ||
| R | Rayo Vallecano | - | UE Lleida | 1:1 | ||
| H: 11.12.1985 | R: 08.01.1986 | Sieger: UE Lleida | ||||
| H | CD Logroñés | - | Racing Santander | 1:1 | ||
| R | Racing Santander | - | CD Logroñés | 3:1 n.V. | ||
| H: 11.12.1985 | R: 08.01.1986 | Sieger: Racing Santander | ||||
| H | CA Osasuna | - | Real Burgos | 1:0 | ||
| R | Real Burgos | - | CA Osasuna | 2:0 n.V. | ||
| H: 11.12.1985 | R: 08.01.1986 | Sieger: Real Burgos | ||||
| H | Real Oviedo | - | Espanyol Barcelona | 2:0 | ||
| R | Espanyol Barcelona | - | Real Oviedo | 3:2 | ||
| H: 11.12.1985 | R: 08.01.1986 | Sieger: Real Oviedo | ||||
| H | Sevilla FC | - | RCD Mallorca | 1:0 | ||
| R | RCD Mallorca | - | Sevilla FC | 0:3 i.E. | ||
| H: 11.12.1985 | R: 08.01.1986 | Sieger: Sevilla FC | ||||
| H | Valencia CF | - | CD Tenerife | 0:1 | ||
| R | CD Tenerife | - | Valencia CF | 3:1 | ||
| H: 11.12.1985 | R: 08.01.1986 | Sieger: CD Tenerife | ||||
| H | Real Zaragoza | - | CD Málaga | 2:0 | ||
| R | CD Málaga | - | Real Zaragoza | 1:1 | ||
| H: 11.12.1985 | R: 14.01.1986 | Sieger: Real Zaragoza | ||||
