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| H | Corinthians SP | - | Flamengo RJ | 0:2 (0:1) | ||
| R | Flamengo RJ | - | Corinthians SP | 1:0 (0:0) | ||
| H: 03.08.2022 02:30 | R: 10.08.2022 02:30 | Sieger: Flamengo RJ | ||||
| H | Vélez Sarsfield | - | Talleres de Córdoba | 3:2 (1:0) | ||
| R | Talleres de Córdoba | - | Vélez Sarsfield | 0:1 (0:0) | ||
| H: 04.08.2022 02:30 | R: 11.08.2022 02:30 | Sieger: Vélez Sarsfield | ||||
| H | Atlético Mineiro | - | Palmeiras | 2:2 (1:0) | ||
| R | Palmeiras | - | Atlético Mineiro | 6:5 (0:0, 0:0) i.E. | ||
| H: 04.08.2022 02:30 | R: 11.08.2022 02:30 | Sieger: Palmeiras | ||||
| H | Athletico Paranaense | - | Estudiantes | 0:0 (0:0) | ||
| R | Estudiantes | - | Athletico Paranaense | 0:1 (0:0) | ||
| H: 05.08.2022 02:30 | R: 12.08.2022 02:30 | Sieger: Athletico Paranaense | ||||
