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| H | River Plate | - | Cruzeiro | 0:0 (0:0) | ||
| R | Cruzeiro | - | River Plate | 2:4 (0:0, 0:0) i.E. | ||
| H: 24.07.2019 00:15 | R: 31.07.2019 00:15 | Sieger: River Plate | ||||
| H | Godoy Cruz | - | Palmeiras | 2:2 (2:1) | ||
| R | Palmeiras | - | Godoy Cruz | 4:0 (0:0) | ||
| H: 24.07.2019 02:30 | R: 31.07.2019 02:30 | Sieger: Palmeiras | ||||
| H | LDU Quito | - | Club Olimpia | 3:1 (1:0) | ||
| R | Club Olimpia | - | LDU Quito | 1:1 (1:1) | ||
| H: 24.07.2019 02:30 | R: 31.07.2019 02:30 | Sieger: LDU Quito | ||||
| H | Nacional | - | Internacional | 0:1 (0:0) | ||
| R | Internacional | - | Nacional | 2:0 (1:0) | ||
| H: 25.07.2019 00:15 | R: 01.08.2019 00:15 | Sieger: Internacional | ||||
| H | San Lorenzo | - | Cerro Porteño | 0:0 (0:0) | ||
| R | Cerro Porteño | - | San Lorenzo | 2:1 (0:1) | ||
| H: 25.07.2019 00:15 | R: 01.08.2019 00:15 | Sieger: Cerro Porteño | ||||
| H | Emelec | - | Flamengo RJ | 2:0 (1:0) | ||
| R | Flamengo RJ | - | Emelec | 4:2 (2:0, 2:0) i.E. | ||
| H: 25.07.2019 02:30 | R: 01.08.2019 02:30 | Sieger: Flamengo RJ | ||||
| H | Athletico Paranaense | - | Boca Juniors | 0:1 (0:0) | ||
| R | Boca Juniors | - | Athletico Paranaense | 2:0 (0:0) | ||
| H: 25.07.2019 02:30 | R: 01.08.2019 02:30 | Sieger: Boca Juniors | ||||
| H | Grêmio Porto Alegre | - | Libertad | 2:0 (0:0) | ||
| R | Libertad | - | Grêmio Porto Alegre | 0:3 (0:3) | ||
| H: 26.07.2019 02:30 | R: 02.08.2019 02:30 | Sieger: Grêmio Porto Alegre | ||||
