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| H | Cúcuta Deportivo | - | Nacional | 2:0 (0:0) | ||
| R | Nacional | - | Cúcuta Deportivo | 2:2 (1:1) | ||
| H: 16.05.2007 04:00 | R: 23.05.2007 01:15 | Sieger: Cúcuta Deportivo | ||||
| H | Defensor Sporting | - | Grêmio Porto Alegre | 2:0 (2:0) | ||
| R | Grêmio Porto Alegre | - | Defensor Sporting | 4:2 (2:0, 2:0, 2:0) i.E. | ||
| H: 17.05.2007 00:30 | R: 24.05.2007 00:15 | Sieger: Grêmio Porto Alegre | ||||
| H | CF América | - | Santos FC | 0:0 (0:0) | ||
| R | Santos FC | - | CF América | 2:1 (0:1) | ||
| H: 17.05.2007 02:45 | R: 24.05.2007 02:45 | Sieger: Santos FC | ||||
| H | Boca Juniors | - | Libertad | 1:1 (0:0) | ||
| R | Libertad | - | Boca Juniors | 0:2 (0:0) | ||
| H: 18.05.2007 02:15 | R: 25.05.2007 02:15 | Sieger: Boca Juniors | ||||
