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| H | Mariscal Sucre | - | Vaca Díez | 2:1 | ||
| R | Vaca Díez | - | Mariscal Sucre | 3:0 | ||
| H: 25.11.2020 20:30 | R: 28.11.2020 | Sieger: Vaca Díez | ||||
| H | Municipal de Tiquipaya | - | Deportivo FATIC | 2:3 | ||
| R | Deportivo FATIC | - | Municipal de Tiquipaya | 2:1 | ||
| H: 25.11.2020 20:30 | R: 28.11.2020 20:30 | Sieger: Deportivo FATIC | ||||
| H | Chaco Petrolero | - | Cochabamba FC | 2:0 | ||
| R | Cochabamba FC | - | Chaco Petrolero | 3:0 | ||
| H: 25.11.2020 20:30 | R: 28.11.2020 20:30 | Sieger: Cochabamba FC | ||||
| H | Rosario Central de Potosí | - | Oruro Royal | 1:1 | ||
| R | Oruro Royal | - | Rosario Central de Potosí | 0:0 | ||
| H: 25.11.2020 20:30 | R: 28.11.2020 20:30 | Sieger: Oruro Royal | ||||
| H | Empresa Minera Huanuni | - | Stormers de Potosí | 3:1 | ||
| R | Stormers de Potosí | - | Empresa Minera Huanuni | 6:2 | ||
| H: 25.11.2020 20:30 | R: 28.11.2020 20:00 | Sieger: Stormers de Potosí | ||||
| H | Satélite Norte | - | Libertad Gran Mamoré | 1:1 | ||
| R | Libertad Gran Mamoré | - | Satélite Norte | 4:1 | ||
| H: 25.11.2020 20:30 | R: 29.11.2020 21:00 | Sieger: Libertad Gran Mamoré | ||||
| H | Quebracho | - | Independiente Petrolero | 3:2 | ||
| R | Independiente Petrolero | - | Quebracho | 5:4 i.E. | ||
| H: 25.11.2020 20:30 | R: 29.11.2020 20:30 | Sieger: Independiente Petrolero | ||||
| H | Fancesa | - | Real Tomayapo | 3:1 | ||
| R | Real Tomayapo | - | Fancesa | 3:1 | ||
| H: 25.11.2020 20:30 | R: 29.11.2020 00:30 | |||||
| H | Deportivo Kivón | - | Torre Fuerte | 2:7 | ||
| R | Torre Fuerte | - | Deportivo Kivón | 1:1 | ||
| H: 26.11.2020 01:00 | R: 28.11.2020 20:30 | Sieger: Torre Fuerte | ||||
