| 1. Spieltag | 09.09.2006 | AS Roma | - | AS Livorno | 2:0 |  |
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| 5. Spieltag | 01.10.2006 | FC Messina | - | AS Livorno | 0:1 | ||||
| 6. Spieltag | 15.10.2006 | Ascoli Calcio | - | AS Livorno | 0:2 | ||||
| 7. Spieltag | 22.10.2006 | AS Livorno | - | AC Siena | 0:0 | ||||
| 8. Spieltag | 25.10.2006 | Inter | - | AS Livorno | 4:1 | ||||
| 10. Spieltag | 05.11.2006 | AS Livorno | - | Udinese Calcio | 1:0 | ||||
| 11. Spieltag | 12.11.2006 | Calcio Catania | - | AS Livorno | 3:2 | ||||
| 12. Spieltag | 19.11.2006 | AS Livorno | - | Parma FC | 3:0 | ||||
| 13. Spieltag | 26.11.2006 | Reggina Calcio | - | AS Livorno | 2:2 | ||||
| 14. Spieltag | 03.12.2006 | AS Livorno | - | Chievo Verona | 0:2 | ||||
| 15. Spieltag | 09.12.2006 | US Palermo | - | AS Livorno | 3:0 | |
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| 17. Spieltag | 20.12.2006 | Sampdoria | - | AS Livorno | 4:1 | |
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| 18. Spieltag | 23.12.2006 | AS Livorno | - | Torino FC | 1:1 | |
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| 20. Spieltag | 21.01.2007 | AS Livorno | - | AS Roma | 1:1 | |
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| 21. Spieltag | 28.01.2007 | ACF Fiorentina | - | AS Livorno | 2:1 | ||||
| 23. Spieltag | 11.02.2007 | AC Milan | - | AS Livorno | 2:1 | ||||
| 31. Spieltag | 07.04.2007 | Parma FC | - | AS Livorno | 1:0 | ||||
| 33. Spieltag | 22.04.2007 | Chievo Verona | - | AS Livorno | 2:1 |
Ghana